Potential sources and meteorological factors affecting PM<Subscript>2.5</Subscript>-bound polycyclic aromatic hydrocarbon levels in six main cities of northeastern Italy: an assessment of the related carcinogenic and mutagenic risks

A yearlong sampling campaign (2012–2013) was conducted in six major cities of the Veneto region to investigate the spatial-temporal trends and the factors affecting the polycyclic aromatic hydrocarbon (PAHs) variations and identify the local sources. Sixty samples per city were collected for analyses in every alternate month (April, June, August, October, December, and February): 10 samples per sampling site in 10 consecutive days of the months selected. Samples were ultrasonically extracted with acetonitrile and processed through high-performance liquid chromatography. Total Σ-PAH concentrations ranged from 0.19 to 70.4 ng m^?3 with a mean concentration of 11.5 ng m^?3. The mean benzo[a]pyrene (BaP) concentration reached 2.0 ng m^?3, which is two-times higher than the limit set by the European Union. BaP contributed for 17.4% to the total concentration of PAHs, which showed the same pattern across the region with maxima during cold months and minima in the warm period. In this study, PAHs showed an inverse relationship with temperature, solar radiation, wind speed, and ozone. According to this study, biomass burning for household heating and cooking, followed by gaseous PAHs absorption on particles due to low atmospheric temperature, were the main reasons for increasing PAHs concentration in winter. Health risk, evaluated as lifetime lung cancer risk (LCR), showed a potential carcinogenic risk from the airborne BaP_TEQ six-fold higher in the cold season than in the warm one. Diagnostic ratios and conditional probability functions were used to locate the sources, and results confirmed that local emission, overall domestic heating, and road transport exhausts were responsible for higher concentration rates of PAHs as well as of PM_2.5.     

Particulate matter concentration levels during intense haze event in an urban environment

This study assessed concentration levels of particulate matter (PM) in the ambient environment of Ilorin metropolis, Nigeria, during haze episodes. Meteorological data (wind speed and direction, rainfall data, sunshine data, relative humidity and temperature) were obtained. Aerocet 531S particle counter (MetOne Instruments, USA) was used to measure four mass concentration ranges of PM (PM_1.0, PM_2.5, PM₁₀ and the total suspended particles (TSP)) in 10 locations taking into consideration land use patterns. Surfer® version 8 (Golden Software LLC, USA) was used to model the spatial variation of particulate matter concentration levels using kriging interpolation griding method. Human exposure assessment was done using the total respiratory deposition dose (TRDD) estimates and statutory limit breach (SLB) approaches. The appearance of dominating weak southern atmospheric wind flow was observed as wind speed ranged from 0 to 6.811 m/s while solar radiation periods ranged from 0.3 to 3.5 h/day. The relative humidity of the metropolis ranged between 28 and 57%, while daily temperature was 15 to 36 °C. Highest concentration levels of PM measured were 73.4, 562.7, 7066.3 and 9907.8 μg/m³ for PM_1.0, PM_2.5, PM₁₀ and TSP, respectively. Very strong negative correlations existed between the PM concentration levels and microclimatic parameters. Spatial variation of the concentration level as modelled using Surfer® version 8 indicated that particulate concentration level increases from south to north. Concentration levels of PM for the 24-h averaging period were generally above the 24-h threshold limit value set by the regulatory agencies for all the locations.     

Relationships between aquatic invertebrate communities,water-level fluctuations and different habitats in a subtropical lake

In lakes, the littoral habitat and its invertebrate communities are often exposed to water-level fluctuations. We examined the effects of seasonal changes on water level, substrata availability and benthic fauna in the littoral zone of Peri Lake, a shallow lake that has experienced a strong reduction in water level due to changes in rainfall. In this study, we also examined whether the abundance and composition of aquatic invertebrates differed among the four substrata. Our main objective was to assess the effect of seasonal changes on water level and benthic invertebrates inhabiting the different types of substrata. Benthic invertebrates were sampled four different substrata (Schoenoplectus californicus, sand and stones, allochthonous leaf litter, and macrophyte stands), and we also measured meteorological, physical and chemical variables. We found that complex habitats, such as allochthonous leaf litter and aquatic macrophyte, stand to be colonised by a larger number of macroinvertebrates because they provide more habitats or potential niches for colonisation by different species. In addition, we observed that during periods of low water level, the presence of substrata in the littoral zone decreased, as did the associated biota. Therefore, our results suggest that water level changes have a major functional impact on the littoral zone of the lake, and can affect substratum availability, which also impacts invertebrate communities.     

Water management and aquatic ecosystem services of a tropical reservoir (Itaparica,São Francisco,Brazil)

Reservoirs have a wide variety of uses that have led to frequent conflicts over ecological conservation and contamination, especially as land management has intensified. Oligotrophication must be implemented in numerous tropical reservoirs that experience advanced eutrophication to maintain aquatic ecosystem functions. To quantify impacts on ecosystem functions and to develop an adaptive management policy, multiple studies have been conducted on the Itaparica Reservoir, São Francisco River, in the semi-arid north-eastern region of Brazil. Here, we add to that existing body of knowledge through investigating how nutrient accumulation is affected by water exchange between the main river flow and Icó-Mandantes Bay. Operational water-level fluctuations in the reservoir create large desiccated littoral areas that release high amounts of nutrients when they are rewetted. In particular, water-level variation promotes proliferation of Egeria densa, a noxious weed, thus elevating trophic levels of the Itaparica Reservoir and Icó-Mandantes Bay. Analysis with a P efficiency model determined 25 μg P L^?1 to be the critical concentration and further indicated that the critical load in both bodies of water have been exceeded. Moreover, intensive fish aquaculture using net cages has led to further overtaxing of the reservoir. We conclude that an effective ecological reservoir management policy must involve oligotrophication, harvesting of noxious water weeds for use as soil amendment in agriculture or biogas production, “blue” aquaculture, and limiting hydroelectric power production based on current water availability.     

Enhanced Interfacial Adhesion and Characterisation of Recycled Natural Fibre-Filled Biodegradable Green Composites

The structural, thermal, mechanical, and biodegradable properties of composite materials made from polylactide (PLA) and agricultural residues (arrowroot (Maranta arundinacea) fibre, AF) were evaluated. Melt blended glycidyl methacrylate-grafted polylactide (PLA-g-GMA) and coupling agent-treated arrowroot fibre (TAF) formed the PLA-g-GMA/TAF composite, which had better properties than the PLA/AF composite. The water resistance of the PLA-g-GMA/TAF composite was greater than that of the PLA/AF composite; the release of PLA in water from the PLA/AF and PLA-g-GMA/TAF composites indicated good biological activity. The PLA-g-GMA/TAF material had better mechanical properties than PLA/AF. This behaviour was attributed to better compatibility between the grafted polymer and TAF. The results indicated that the T_g of PLA was increased by the addition of fibre, which may have improved the heat resistance of PLA. Furthermore, the mass losses following burial in soil compost indicated that both materials were biodegradable, especially at high levels of AF or TAF substitution.     

Systemic design for sustainability

How can we restore the ecological balance of our planet? The present article is aimed at contributing a structural framework for such a restoration. In the quest for ecological recovery, cybernetic–systemic approaches are in demand. They specialize in coping with complexity and offer new, transdisciplinary and non-reductionist ways of system design for renewing sustainability. This contribution uses a proven model from organizational cybernetics—the viable system model—as a frame for sustainable development. The model specifies how the viability of any human or social system can be achieved by means of clearly defined organizational structures. In accord with the logic of recursive organization inherent in the model, a proposal for a structural design aimed at enabling ecological recovery is formulated. That design includes all organizational levels of recursion, from individual to world. The implications of such a novel approach are far-reaching, and the impact powerful.     

Overcoming barriers to sustainability by combining conceptual,visual, and networking systems

Sustainability challenges rarely align with the conventional boundaries of our disciplines, institutions and means of communication. To address these challenges amid real-world complexity, we need to think holistically and collaborate across disciplines. In this paper, we synthesise three themes: (1) more integrated conceptual frameworks; (2) digital visual communication which provides fluid expression of complex ideas and perceptions; and (3) online networks which can empower sustainability initiatives and communicate them across social and institutional barriers at a global scale. Each of these tools can help to overcome persistent barriers to sustainability. When used together, they provide a strategic basis for the design of digital collaboration platforms for addressing sustainability challenges. Using design thinking, we developed a Synergy Map which identifies relationships among a number of barriers to sustainability and conceptual and digital tools which help to address them. The Map identifies the potential for synthesising these tools into effective digital artefacts. We provide several examples and identify characteristics of particular value for overcoming barriers to sustainability. Combining new theoretical developments in sustainability sciences with recent advances in communication and networking technologies offers substantial potential for advancing sustainability on multiple fronts.     

Improved desalination by polyamide membranes containing hydrophilic glutamine and glycine

Environmental Chemistry Letters - Water desalination and recycling of wastewater is a key challenge to meet water shortage issues. Thin film composite polyamide membranes are widely used for...     

Life cycle of PCBs and contamination of the environment and of food products from animal origin

This report gives a summary of the historic use, former management and current release of polychlorinated biphenyls (PCBs) in Germany and assesses the impact of the life cycle of PCBs on the contamination of the environment and of food products of animal origin. In Germany 60,000 t of PCBs were used in transformers, capacitors or as hydraulic oils. The use of PCB oils in these “closed applications”, has been banned in Germany in 2000. Thirty to 50% of these PCBs were not appropriately managed. In West Germany, 24,000 t of PCBs were used in open applications, mainly as additive (plasticiser, flame retardant) in sealants and paints in buildings and other construction. The continued use in open applications has not been banned, and in 2013, an estimated more than 12,000 t of PCBs were still present in buildings and other constructions. These open PCB applications continuously emit PCBs into the environment with an estimated release of 7–12 t per year. This amount is in agreement with deposition measurements (estimated to 18 t) and emission estimates for Switzerland. The atmospheric PCB releases still have an relevant impact on vegetation and livestock feed. In addition, PCBs in open applications on farms are still a sources of contamination for farmed animals. Furthermore, the historic production, use, recycling and disposal of PCBs have contaminated soils along the lifecycle. This legacy of contaminated soils and contaminated feed, individually or collectively, can lead to exceedance of maximum levels in food products from animals. In beef and chicken, soil levels of 5 ng PCB-TEQ/kg and for chicken with high soil exposure even 2 ng PCB-TEQ/kg can lead to exceedance of EU limits in meat and eggs. Areas at and around industries having produced or used or managed PCBs, or facilities and areas where PCBs were disposed need to be assessed in respect to potential contamination of food-producing animals. For a large share of impacted land, management measures applicable on farm level might be sufficient to continue with food production. Open PCB applications need to be inventoried and better managed. Other persistent and toxic chemicals used as alternatives to PCBs, e.g. short chain chlorinated paraffins (SCCPs), should be assessed in the life cycle for exposure of food-producing animals and humans.